Anyone who has been through a high school science class will
likely be familier with the term osmosis. The process first described by a
French Scientist in 1748, who noted that water spontaneously diffused through a
big bladder membrane into alcohal. Over 200 years later, a modification of the
process known as reverse osmosis allows peop throughout the world to affordably
convert undesirable water that is virtually free of health or aesthatic
contaminants. Reverse osmosis systems can be found providing treated water from
the kitchen counter in a private residence to installations used in manned
spacecraft.
Reverse Osmosis is a technology that is found virtually anywhere
pure water is needed; common uses include:
Drinking Water
Humidification
Ice-Making
Car Wash Water Reciamation
Rinse Waters
Biomedical Applications
Laboratory Applications
Photography
Pharmaceutical Production
Kidney Dialysis
Water used in chemical processes
Cosmotics
Animal Feed Hatcheries
Restaurants
Greenhouses
Metal Plating Applications
Wastewater Treatment
Boiler Water
Battery Water
Semiconductor production
Hemodialysis
How Reverse Osmosis Works.
A semipermeable membrane, like the membrane of a cell wall or a
bladder, is selective about what it allows to pass through, and what it
prevents from passing. These membranes in general pass water very easily
because of its small molecular size; but also prevent many other
contaminants from passing by trapping them. Water will typically be
present on both sides of the membrane, with each side having a different
concentration of dissolved minerals. Since the less concentrated
solution seeks to dilute the more concentrated solution, water will pass
through the membrane the lower concentration side to the greater
concentration side. Eventually, osmotic pressure (seen in the diagram
below as the pressure created by the difference in water levels) will
counter the diffusion process exactly, and an equilibrium will form.
The process of reverse osmosis forces water with a greater
concentration of contaminants (the source water) into a containing water
with an extremely low concentration of contaminants (the processed
water). High water pressure of source side is used to
"reverse" the natural osmoic process, with the semi-permeable
membrane still permitting the passage of water while rejecing most of
the other contaminants. The specific process through which this occurs
is an ion exclusion, in which a concentration ions at the membrane
surface form a barrier that allows other water molecules to pass through
while excluding other substances.
Semipermeable membranes have come a logn way from the natural pig
bladders used in the earlier osmosis experiments. Before the 1960's,
these membranes were too inefficient, expensive, and unreliable for
practical applications outside the laboratory. Modern advances
insystematic materials have generally solved these problems., allowing
membranes to become highly efficient at rejecting contaminants, and
making them tough enough to withstand the greater pressures necessay for
efficient operation.
Even with these advances, the "reject" water on the source
side of Reverse Osmosis (RO) system must be periodically flushed in
order to keep it from becoming so concentrated that it forms a scale on
the membrane itself. RO systems typically require a carbon prefilter for
the reduction of chlorine , which can damage an RO membrane; and a
sedime prefilter is always required to ensure that fine suspended
materials in the source water do not permanently clog the membrane,
Hardness reduction, either through the use of water softening for
residential units or chemical softening industrial use, may also be
desirable in hard water areas.
Low Pressure (Residential) Systems
Low pressure RO systems generally refer to those systems with a water
feed pressure of less than 100 psig. These the typical countertop or
undersink residential systems that rely primarily on the natural water
pressure to make the reverse osmosis process function; a typical system
is shown schematically below.
Contertop units typically have an unpressurized storage
tank; Undersink units typically have a pressurized accumulation storage
tank where the water pressure tends to increase as the tank fills. This
pressurized system provides sufficient pressure to move the water from the
undersink storage tank to faucet. Unfortunately, this also creates a back
pressure against the membrane, which can decrease its efficiency. Some
units overcome this by using unpressurized tanks with a pump to get the
treated water where it is needed.
Low pressure units typically provide between 2 and 15
gallons per day of water, with an efficiency of 2-4 gallons of Raw water
per gallon of treated water. Water purity can be as high as 95 percent.
These systems can be highly affordable with countertop units starting at
about US $350, and undersink units starting at about US $600. These
units produce water for a cost as low as ten cents per gallon once
maintenance and water costs are factored in. Maintenance usually requires
replacing any pre- or postfilters (typically one to four times per year);
and the reverse osomosis cartridge on every two to three years, depending
on usage. Look for the WQA Gold Seal (S-300) to find products that have
been successfully tested to industry performance standards; and to
Certified Water Specialists (CWS I-V), Certified Sales Representatives
(CSR), Certified Installers (CI) for advice on your water needs, and
equipment installation.
High pressure systems typically operate at pressures
between 100 and 1000 psig, depending on the membranes conditions and the
water being treated. These systems are usually used in industrial or
commercial apllications where large volumes of treated water are required
at a high level of purity.
Most commercial and industrial systems use multiple
membranes arranged in parallel to provide the required quant water. The
processed water from the first stage of treatment can then be passed
through additional membrane module membrane modules for greater efficiency
(see diagram below), though flushing will still be required when
concentration reach a level where fouling is likely to occur
Commercial Multiple Membrane
Module RO System
High pressure indutrial units typically provide from 10
gallons to thousands of gallons per day of water with an efficiency of 1-9
gallons of reject water per gallon of treated water. Water purity can be
as high as 95 percent. These systems to be larger and more complicated
than low pressure systems, and this is reflected in their costs, which
range from $1000 through tens of thousands of dollars for a large,
multi-module unit capable of providing desalinated drinking water for a
resort facility or water bottling plant.
What Reverse Osmosis Treats
Reverse osmosis can treat for a wide variety of health and
aesthatic contaminants. Effectively designed, RO equipment can treat for a
wide variety of aesthatic contaminants that cause unpleasant taste, color,
and odor problems like a sour soda taste caused by chlorides or sulfates.
RO can also be effective for treating health contaminants
like arsenic, asbestos, astrazine (herbicides/pesticides), fluoride, lead,
mercury, nitrate, and radium. When using appropriate carbon prefiltering
(commonly included with most RO systems), additional treatment can also be
provided for such "volatile" contaminants as benzene,
trichloroethylene, trihalomethanes, and radon. Some RO equipment is also
capable of treating for biological contaminants like Cryptosporidium. The
Water Quality Association (WQA) cautions, however, that while RO membranes
typically remove virtually all known microorganisms and most other health
contaminants, design considerations may prevent a unit from offering
foolproof protection when incorporated into a consumer drinking water
syatem.
When looking for a product to treat for a given health
contaminants, care should be used to find products that have been tested
successfully for such purposes at a quality testing laboratory.
Conclusion
Reverse osmosis is a relatively new, but very effective,
application of an established scientific process. Whether it is to meet
the needs of a typical family of four, or the needs of an industrial
operation requiring thousands of gallons per day, it can be a cost
effective to provide the required quantity of highly treated water. With
continual advances in systems and membrane design that boost efficiency
and reliability, RO can be expected to play a major role in water
treatment years to come.